Inorganic electrosynthesis: a green chemical method for tin complexes

Jiménez Pérez, Víctor M. y Muñoz Flores, Blanca M. y Kharisov, Boris I. y Hernández Fernández, Eugenio y López Cortina, Susana y Waksman de Torres, Noemí y Ramírez Durón, Rosalba (2011) Inorganic electrosynthesis: a green chemical method for tin complexes. Revista Química Hoy, 1 (3). pp. 30-33. ISSN 2007-1183

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Resumen

Sn complexes of the series of bulky amines have been reported by electrochemical oxidation (3 h) of a tin anode in a cell containing methanol solution of the corresponding bulky amine. All were full characterized by 'H and C-NMR, IR and high resolution mass spectrometry. However, all were not enough soluble in organic colvent in order to record its Sn-NMR spectra, this unusual behavior was attributed to the polymeric association thought intermolecular coordination OSn.

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