"One pot" microwave assisted synthesis of 5,10,15-tri(4-methoxyphenyl)-20-(4-chlorophentyl)-21H,23H-porphyrin and its zinc (II) complex

Loredo Calderón, Erika Lilián y Martínez Lejia, Carolina y López Cortina, Susana y Muñoz Flores, Blanca M. y Hernández Fernández, Eugenio y Jiménez Pérez, Víctor M. y Cuevas Yañez, Erick (2012) "One pot" microwave assisted synthesis of 5,10,15-tri(4-methoxyphenyl)-20-(4-chlorophentyl)-21H,23H-porphyrin and its zinc (II) complex. Química Hoy, 2 (2). pp. 6-9. ISSN 2007-1183

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Resumen

The synthesis of new unsymmetrical A3B porphyrin, 5,10,15-tri(4-methoxyphenyl)-20-(4-chlorophentyl)-21H,23H-porphyrin, 1, and its zinc(II) complex, 5,10,15-tri(4-methoxyphenyl)-20-(4-chlorophentyl)-21,23-Zinc(II)-porphine, 2, was accomplished using both conventional and "one pot" solventless microwave assisted methods with interesting comparative results. The obtained molecules were characterized by H NMR, UV-Vis and MS. These molecules are considered to represent new compounds with potential application as photosensitizers in photodynamic therapy.

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