Polyaza macroligands as potential agents for heavy metal removal from wastewater

Elizondo, Martínez y Nájera, Martínez y Pérez, Rodríguez y Reyes, Hinojosa y Río, Del (2013) Polyaza macroligands as potential agents for heavy metal removal from wastewater. Journal of the Serbian Chemical Society, 78 (4). pp. 591-602. ISSN 0352-5139

Vista previa

Texto 518.pdf - Versión Publicada Available under License Creative Commons Attribution Non-commercial No Derivatives. Download (335kB) | Vista previa

Resumen

Two polyaza macroligands N,N´-bis(2-aminobenzyl)-1,2-ethanediamine (L1) and 3,6,9,12-tetraaza-4(1,2),11(1,2)-dibenzo-1(1,3)-pyridinacyclotridecaphane (L2) were characterized and investigated for their metal ion extraction capabilities. The nature of all complexes was established by spectroscopic techniques. The equilibrium constants were determined by spectrophotometric and potentiometric techniques and the residual concentration of metals in the solutions by atomic absorption spectrometry (AAS). The capacity of the ligands to remove heavy metals such as Cu(II), Ni(II), Cd(II), Zn(II) and Pb(II) as insoluble complexes was evaluated in wastewater from industrial effluents. These agents showed high affinity for the studied metals. The values of the equilibrium constants of the isolated complexes (between 1×104 and 2×107) demonstrated the feasibility of applying these chelating agents as alternatives for the removal of heavy metals from industrial effluents.

Actions (login required)

Ver elemento